Aminolysis of bis[bis(trimethylsilyl)amido]-manganese, -iron, and -cobalt for the synthesis of mono- and bis-silylene complexes.,Dalton Transactions

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Aminolysis of bis[bis(trimethylsilyl)amido]-manganese, -iron, and -cobalt for the synthesis of mono- and bis-silylene complexes.
Dalton Transactions ( IF 3.5 ) Pub Date : 2020-08-15 , DOI: 10.1039/d0dt00570c
Zhiyuan He ₁ , Xiaolian Xue ₂ , Yilan Liu ₂ , Na Yu ₂ , Jeremy P Krogman ₂

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We report a method for the synthesis of amidinate stabilized silylene (NHSi) metal–halide complexes from M{N(SiMe₃)₂}₂ (M = Mn, Fe, Co). The reported reactions can be used to make mono-silylene or bis-silylene complexes and the resulting products can be easily controlled by the reaction stoichiometry. Additionally, we apply this new synthetic protocol for the synthesis of a bis-iron complex derived from a bis-amidinate ligand having a terphenyl backbone.

中文翻译：

双[双（三甲基甲硅烷基）酰胺基]-锰，-铁和-钴的氨解反应，用于合成单-和双-亚甲硅烷基配合物。

我们报告了一种从M {N（SiMe ₃）₂ } ₂（M = Mn，Fe，Co）合成of胺稳定的亚甲硅烷基（NHSi）金属卤化物配合物的方法。所报道的反应可用于制备单亚甲硅烷基或双亚甲硅烷基络合物，并且所得的产物可通过反应化学计量容易地控制。此外，我们将这种新的合成方案应用于合成具有铁联骨架的双-酰胺配体的双铁配合物。

更新日期：2020-09-22

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