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Multi-stage spark plasma sintering to study the densification mechanisms of boron carbide
International Journal of Refractory Metals & Hard Materials ( IF 4.2 ) Pub Date : 2020-08-15 , DOI: 10.1016/j.ijrmhm.2020.105351
Yingjie Zhang , Mei Zhang , Zhihui Zhou , Minbo Wang , Siyao Xie , Yanzhong Zhao , Yunbao Xu , Tiechui Yuan , Ruidi Li

The densification kinetics of boron carbide (B4C) during multi-stage spark plasma sintering was studied. The densification mechanisms were analyzed according to the stress exponent n and the apparent activation energy Qd using a creep deformation model. The results showed that the densification mechanisms were controlled by viscous flow and grain boundary diffusion at the low effective stress with initial temperature range of 1600–2000 °C, while the dominant mechanism is the dislocation climb at the effective stress regime with final temperature of 2100 °C and the multi-stage sintering can reduce the apparent activation energy. Meanwhile, the scheme of multi-stage sintering can obtain nearly theoretical dense B4C and avoid grain growth. Therefore, the basic mechanical properties suggesting a good combination of high hardness (37.63GPa) and bending strength (539.86 MPa) was obtained by the multi-stage sintering.



中文翻译:

多级火花等离子体烧结研究碳化硼的致密化机理

研究了多阶段火花等离子体烧结过程中碳化硼(B 4 C)的致密化动力学。利用蠕变变形模型根据应力指数n和表观活化能Q d分析了致密化机理。结果表明,在低有效应力条件下(初始温度为1600-2000°C),致密化机制受粘性流和晶界扩散的控制,而主要机制是在有效应力条件下(最终温度为2100)的位错爬升。 °C和多阶段烧结可以降低表观活化能。同时,多阶段烧结方案可以得到接近理论密度的B 4。C,避免谷物生长。因此,通过多阶段烧结获得了基本机械性能,表明高硬度(37.63GPa)和抗弯强度(539.86 MPa)的良好组合。

更新日期:2020-08-15
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