当前位置: X-MOL 学术Funct. Mater. Lett. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
A comparative study of Li10.35Ge1.35P1.65S12 and Li10.5Ge1.5P1.5S12 superionic conductors
Functional Materials Letters ( IF 1.2 ) Pub Date : 2020-06-23 , DOI: 10.1142/s1793604720500319
Yue Jiang 1 , Zhiwei Hu 1 , Ming’en Ling 1 , Xiaohong Zhu 1
Affiliation  

Since the lithium-ion conductor Li[Formula: see text]GeP2S[Formula: see text] (LGPS) with a super high room-temperature conductivity of 12[Formula: see text]mS/cm was first reported in 2011, sulfide-type solid electrolytes have been paid much attention. It was suggested by Kwon et al. [J. Mater. Chem. A 3, 438 (2015)] that some excess lithium ions in LGPS, namely, Li[Formula: see text]Ge[Formula: see text] P[Formula: see text]S[Formula: see text], could further improve their ionic conductivities, and the highest conductivity of 14.2[Formula: see text]mS/cm was obtained at [Formula: see text] though a larger lattice parameter that occurred at [Formula: see text]. In this study, we focus on these two different chemical compositions of LGPS with [Formula: see text] and [Formula: see text], respectively. Both samples were prepared using the same experimental process. Their lattice parameter, microstructure and room-temperature ionic conductivity were compared in detail. The results show that the main phase is the tetragonal LGPS phase but with a nearly identical amount of orthorhombic LGPS phase coexisting in both samples. Bigger lattice parameters, larger grain sizes and higher ionic conductivities are simultaneously achieved in Li[Formula: see text]Ge[Formula: see text]P[Formula: see text]S[Formula: see text] ([Formula: see text]), exhibiting an ultrahigh room-temperature ionic conductivity of 18.8[Formula: see text]mS/cm.
更新日期:2020-06-23
down
wechat
bug