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Investigation on single crystal by tartaric acid–barium chloride: growth and characterization of novel NLO materials
Bulletin of Materials Science ( IF 1.9 ) Pub Date : 2020-08-12 , DOI: 10.1007/s12034-020-02176-6
S Shanmugan , N Saravanan , V Chithambaram , B Deepanraj , Geetha Palani

The progress of single crystal followed by C 4 H 6 O 6 (tartaric acid) and BaCl 2 (barium chloride) (TABC; third-order nonlinear optics semi-organic) was synthesized with slow evaporation method using distilled water at room temperature. TABC single crystal was introduced into various characterizations like X-ray diffraction to determine inter atomic cell parameter values. The samples are crystalline structure of monoclinic, which have space group of P 2 . The functional groups of the current material are identified using FT-IR spectrum. Optical parameters like transparency, energy bandgap and Urbach energy have been determined using UV–vis–NIR spectrum. The thermal stability of the material was investigated by differential scanning calorimeter analysis. The mechanical property was studied using Vickers microhardness test. The surface morphology of the material was determined by scanning electron microscope technique. The change in dielectric behaviour of TABC with respect to the function of frequency at various temperatures has been keenly absorbed and discussed. The third-order nonlinear optical parameters were measured using Z-scan analyses.

中文翻译:

酒石酸-氯化钡对单晶的研究:新型非线性光学材料的生长和表征

在室温下用蒸馏水缓慢蒸发合成了单晶,然后是 C 4 H 6 O 6 (酒石酸)和 BaCl 2 (氯化钡)(TABC;三阶非线性光学半有机)。将 TABC 单晶引入各种表征,如 X 射线衍射,以确定原子间细胞参数值。样品为单斜晶体结构,空间群为P 2 。使用 FT-IR 光谱识别当前材料的官能团。光学参数如透明度、能带隙和 Urbach 能量已使用 UV-vis-NIR 光谱确定。通过差示扫描量热仪分析研究材料的热稳定性。力学性能采用维氏显微硬度试验研究。通过扫描电子显微镜技术测定材料的表面形貌。在不同温度下,TABC 介电行为随频率函数的变化已被广泛吸收和讨论。使用 Z 扫描分析测量三阶非线性光学参数。
更新日期:2020-08-12
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