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Stabilisation of tri-valent ions with a vacant coordination site at a corrole-metal interface.
Chemical Communications ( IF 4.3 ) Pub Date : 2020-08-11 , DOI: 10.1039/d0cc03947k
P S Deimel 1 , P Casado Aguilar 1 , M Paszkiewicz 1 , D A Duncan 2 , J V Barth 1 , F Klappenberger 1 , W Schöfberger 3 , F Allegretti 1
Affiliation  

By exploiting an established on-surface metallation strategy, we address the ability of the corrolic macrocycle to stabilise transition metal ions in high-valent (III) oxidation states in metal-supported molecular layers. This approach offers a route to engineer adsorbed metal complexes that cannot be easily fabricated by organic synthesis methods and bear a vacant axial coordination site for catalytic conversions.

中文翻译:

稳定的三价离子在腐蚀剂-金属界面处具有空位配位点。

通过利用已建立的表面金属化策略,我们研究了大环金属在金属负载的分子层中以高价(III)氧化态稳定过渡金属离子的能力。这种方法提供了一种工程来设计吸附的金属络合物的途径,这些金属络合物不能通过有机合成方法轻易地制备,并且具有空的轴向配位位点以进行催化转化。
更新日期:2020-09-24
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