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Spectral properties and Judd–Ofelt analysis of novel red phosphors Gd2InSbO7:Eu3+ with high color purity for white LEDs
Journal of Rare Earths ( IF 5.2 ) Pub Date : 2020-08-08 , DOI: 10.1016/j.jre.2020.08.002
Yu Wang , Baokui Zhao , Bin Deng , Shanshan Chen , Yuanyuan Liu , Guodong Wang , Ruijin Yu

Gd2InSbO7:Eu3+ red phosphors were successfully synthesized via high-temperature solid–state reaction. The phase purity, particle size, and luminescence properties of obtained phosphors were measured and analyzed in detail. The Gd2InSbO7 lattice possesses cubic structure with Fd-3m (227) space group. The phosphors emit bright red emission at 628 nm under 393 nm excitation, and this phenomenon is attributed to the 5D07F2 transition. The Judd–Ofelt parameters (Ω2, Ω4), transition ratio, and branching ratios (β) of Eu3+-doped Gd2InSbO7 phosphor were calculated on the basis of the emission spectra and decay lifetimes. The optimal content in Gd2InSbO7:xEu3+ is identified to be 15 mol%. The thermal quenching of Gd2InSbO7:Eu3+ is found to be over 500 K, and its activation energy is 0.26 eV. The Commission Internationale de l'Eclairage (CIE) chromaticity coordinates of Gd2InSbO7:15%Eu3+ are (0.629, 0.371), which are close to ideal red chromaticity coordinates (0.670, 0.330). The fabricated w-LED exhibits good color rendering index (Ra) (86), correlated color temperature (CCT) (6997 K), and CIE chromaticity coordinates (0.302, 0.330). The obtained results demonstrate that Gd2InSbO7:Eu3+ phosphors have potential applications in white LEDs.



中文翻译:

用于白光 LED 的具有高色纯度的新型红色荧光粉 Gd2InSbO7:Eu3+ 的光谱特性和 Judd-Ofelt 分析

Gd 2 InSbO 7 :Eu 3+红色荧光粉通过高温固相反应成功合成。对所得荧光粉的相纯度、粒径和发光性能进行了详细测量和分析。Gd 2 InSbO 7晶格具有立方结构,具有F d- 3 m (227) 空间群。荧光粉在 393 nm 激发下发出 628 nm 的亮红色发射,这种现象归因于5 D 07 F 2跃迁。Judd–Ofelt 参数 ( Ω 2 , Ω 4)、Eu 3+掺杂的Gd 2 InSbO 7磷光体的跃迁比和分支比( β )基于发射光谱和衰变寿命计算。Gd 2 InSbO 7 : x Eu 3+ 中的最佳含量被确定为15 mol%。发现Gd 2 InSbO 7 :Eu 3+的热猝灭超过500 K,其活化能为0.26 eV。Gd 2 InSbO 7 :15%Eu 3+ 的The Commission Internationale de l'Eclairage (CIE) 色度坐标是 (0.629, 0.371),接近理想的红色色度坐标 (0.670, 0.330)。制造的 w-LED 表现出良好的显色指数 ( R a ) (86)、相关色温 (CCT) (6997 K) 和 CIE 色度坐标 (0.302, 0.330)。所得结果表明Gd 2 InSbO 7 :Eu 3+荧光粉在白光LED中具有潜在的应用。

更新日期:2020-08-08
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