Rational Design of Metal–Organic Frameworks towards Efficient Electrocatalysis,ACS Materials Letters

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Rational Design of Metal–Organic Frameworks towards Efficient Electrocatalysis
ACS Materials Letters ( IF 9.6 ) Pub Date : 2020-08-07 , DOI: 10.1021/acsmaterialslett.0c00229
Shuo Dou ₁ , Xiaogang Li ₁ , Xin Wang ₁

Affiliation

Electrocatalysts play crucial roles in the electrochemical energy conversion systems. Metal–organic frameworks (MOFs), not their high-temperature pyrolysis derived materials, have attracted great attention as electrocatalysts in recent years, because of their large specific surface area, rich pore structure, and uniformly dispersed active sites. Although there are already some review articles focusing on MOFs as electrocatalysts, most of them are mainly based on the applications of MOFs to illustrate their capability and superiority in electrocatalysis. This Review highlights the effective strategies to obtain highly efficient MOFs electrocatalyst from the perspective of material design. Benefitting from the strategies of geometrically structural configuration, coordinatively unsaturated metal sites engineering, metal nodes/ligands optimization, or the electrical conductivity and stability enhancement in the recent progress, MOFs can be improved to exhibit potential for the practical applications in the renewable electrochemical energy conversion systems.

中文翻译：

合理设计金属-有机骨架以实现高效电催化

电催化剂在电化学能量转换系统中起关键作用。由于金属-有机骨架（MOFs）比表面积大，孔结构丰富且活性位点均匀分散，金属-有机骨架（MOFs）而非其高温热解衍生的材料作为电催化剂近年来受到了广泛的关注。尽管已经有一些针对MOF作为电催化剂的评论文章，但大多数文章主要基于MOF的应用来说明其在电催化方面的能力和优越性。本文从材料设计的角度重点介绍了获得高效MOFs电催化剂的有效策略。受益于几何结构配置，协调不饱和金属位点工程，金属节点/配体优化，

更新日期：2020-09-08

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