Abstract A new zero-dimensional (0D) silver (I) chloride based coordination complex 0 D-Ag2Cl2(L) (1, L = (oxybis(2,1-phenylene))bis(diphenylphosphine)) has been prepared by mixing the silver(I) salt and a bidentate P-ligand at room temperature in solution. 1exhibits a band gap of 3.5 eV and a decomposition temperature (Td) of 280 °C. Such a high Td for molecular complex is a result of the strong Ag-P bonding and the “chelating effect” of the metal of the bidentate P-ligand. It has been used as an efficient photocatalyst for the degradation of organic dyes in water.

中文翻译：

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高度稳定的银 (I) 配位络合物作为有效光催化剂降解水中有机染料

摘要 一种新的零维 (0D) 氯化银 (I) 基配位络合物 0 D-Ag2Cl2(L) (1, L = (oxybis(2,1-phenylene))bis(diphenylphosphine))银 (I) 盐和双齿 P 配体在室温下在溶液中。图 1 的带隙为 3.5 eV，分解温度 (Td) 为 280 °C。分子复合物的如此高的 Td 是强 Ag-P 键合和双齿 P-配体金属的“螯合效应”的结果。它已被用作降解水中有机染料的有效光催化剂。