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The Pincer Platform Beyond Classical Coordination Patterns
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2020-08-07 , DOI: 10.1002/ejic.202000513 Matthias Vogt 1 , Robert Langer 2
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2020-08-07 , DOI: 10.1002/ejic.202000513 Matthias Vogt 1 , Robert Langer 2
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The pincer platform provides increased stability and often a rigid coordination mode in transition metal complexes that allows for the incorporation of reactive functional groups in the coordination sphere of a metal. Classical coordination patterns in pincer‐type complexes were established over the past decades, involving a preferred set of binding sites. In the current review, we discuss pincer‐type ligands with remarkable bonding situations and reactivity patterns, which are beyond the privileged ligand systems frequently used in homogeneous catalysis and bond activation reactions. This includes ligands with ligating atoms based on metalloid elements, π‐systems as well as different kinds of metallo‐ligands. We categorize the discussed pincer‐type ligands herein according to the covalent bond classification and distinguish between metallo‐ligands and ligands, which are based on nonmetal and metalloid elements.
中文翻译：
超越经典协调模式的Pincer平台
夹钳平台提供了更高的稳定性，并且在过渡金属络合物中通常提供刚性配位模式，从而允许在金属的配位范围内引入反应性官能团。过去数十年来，在钳型复合物中建立了经典的配位模式，其中涉及一组首选的结合位点。在当前的综述中，我们讨论具有明显键合情况和反应模式的钳型配体，这超出了均相催化和键活化反应中常用的特权配体体系。其中包括具有基于准金属元素，π系统以及不同种类的金属配体的连接原子的配体。
更新日期：2020-08-07
中文翻译：
超越经典协调模式的Pincer平台
夹钳平台提供了更高的稳定性，并且在过渡金属络合物中通常提供刚性配位模式，从而允许在金属的配位范围内引入反应性官能团。过去数十年来，在钳型复合物中建立了经典的配位模式，其中涉及一组首选的结合位点。在当前的综述中，我们讨论具有明显键合情况和反应模式的钳型配体，这超出了均相催化和键活化反应中常用的特权配体体系。其中包括具有基于准金属元素，π系统以及不同种类的金属配体的连接原子的配体。
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