Room-Temperature Pd-Catalyzed Synthesis of 1-(Hetero)aryl Selenoglycosides.,Organic Letters

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Room-Temperature Pd-Catalyzed Synthesis of 1-(Hetero)aryl Selenoglycosides.
Organic Letters ( IF 4.9 ) Pub Date : 2020-08-06 , DOI: 10.1021/acs.orglett.0c02352
Mingxiang Zhu ₁ , Mouad Alami ₁ , Samir Messaoudi ₁

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A general protocol for functionalization of an anomeric selonate anion at room temperature has been reported. By using the PdG3 XantPhos catalyst, the cross-coupling between the in situ-generated glycosyl selenolate and a broad range of (hetero)aryl and alkenyl iodides furnished a series of functionalized selenoglycosides in excellent yields with perfect control of the anomeric configuration.

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