Sequential Suzuki-Miyaura Coupling/Lewis Acid-Catalyzed Cyclization: An Entry to Functionalized Cycloalkane-Fused Naphthalenes.,Organic Letters

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Sequential Suzuki-Miyaura Coupling/Lewis Acid-Catalyzed Cyclization: An Entry to Functionalized Cycloalkane-Fused Naphthalenes.
Organic Letters ( IF 4.9 ) Pub Date : 2020-08-05 , DOI: 10.1021/acs.orglett.0c02020
Camilo Mahecha-Mahecha _{1,

2} , Frédéric Lecornué ₁ , Sumita Akinari _{1,

3} , Thomas Charote ₁ , Diego Gamba-Sánchez ₂ , Tomohiko Ohwada ₃ , Sébastien Thibaudeau ₁

Affiliation

Functionalized angular cycloalkane-fused naphthalenes were prepared using a two-step process involving a Pd-catalyzed Suzuki–Miyaura coupling of aryl pinacol boronates and vinyl triflates followed by a boron trifluoride etherate-catalyzed cycloaromatization.

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