Transition Metal-Catalyzed Selective Carbon-Carbon Bond Cleavage of Vinylcyclopropanes in Cycloaddition Reactions.,Chemical Reviews

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Transition Metal-Catalyzed Selective Carbon-Carbon Bond Cleavage of Vinylcyclopropanes in Cycloaddition Reactions.
Chemical Reviews ( IF 51.4 ) Pub Date : 2020-08-05 , DOI: 10.1021/acs.chemrev.0c00160
Jianhua Wang ₁ , Stephanie A Blaszczyk _{2,

3} , Xiaoxun Li ₁ , Weiping Tang _{2,

3}

Affiliation

In this review, transition metal-catalyzed methodologies and applications that exploit C–C bond cleavage of vinylcyclopropanes (VCPs) are summarized with a focus on cycloaddition and related addition reactions. Transition metals, including palladium, nickel, iron, ruthenium, rhodium, cobalt, and iridium, can catalyze the cleavage of C–C bonds in activated or nonactivated VCPs. Additionally, these bond-breaking reactions can occur as intra- or intermolecular processes. The properties of activated and nonactivated VCPs are discussed in the Introduction. Various transition metal-catalyzed cycloaddition and addition reactions involving the cleavage of C–C bonds in activated VCPs are then discussed in the next chapter. The transition metal-catalyzed cycloadditions involving the cleavage of C–C in nonactivated VCPs are summarized in the following chapter. Finally, challenges and potential opportunities are outlined in the last chapter.

中文翻译：

环加成反应中乙烯基环丙烷的过渡金属催化选择性碳-碳键断裂。

在这篇综述中，总结了利用乙烯基环丙烷 (VCP) C-C 键断裂的过渡金属催化方法和应用，重点关注环加成和相关加成反应。过渡金属，包括钯、镍、铁、钌、铑、钴和铱，可以催化活化或非活化 VCP 中 C-C 键的断裂。此外，这些断键反应可以作为分子内或分子间过程发生。引言中讨论了活化和非活化 VCP 的特性。各种过渡金属催化的环加成反应和涉及活化 VCP 中 C-C 键断裂的加成反应将在下一章讨论。涉及非活化 VCP 中 C-C 裂解的过渡金属催化环加成反应将在下一章中进行总结。最后，最后一章概述了挑战和潜在机遇。

更新日期：2020-08-05

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