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Aging stability of bio-oil produced from dewatered sewage sludge in subcritical water
The Journal of Supercritical Fluids ( IF 3.9 ) Pub Date : 2020-08-06 , DOI: 10.1016/j.supflu.2020.105011
Rana Mujahid , Jaehoon Kim

In this study, the stability of bio-oil produced from the hydrothermal liquefaction of dewatered sewage sludge was examined under room-temperature and accelerated-aging conditions at 80 °C over 6 months. No significant change was observed in the fluidity, viscosity, or molecular weight of the room-temperature bio-oil samples. The accelerated-aged bio-oil samples maintained their fluidity for up to 1 week, and substantial increases in the viscosity and molecular weight were observed in the samples aged for more than 1 month. Additionally, the decomposition behaviors of the room-temperature-aged samples were considerably similar to that of fresh bio-oil, whereas the low-temperature decomposition peak at 86 °C progressively decreased and shifted toward the high-temperature direction with increasing accelerated-aging time. The composition analyses of the aged bio-oil samples indicated that low-molecular-weight species, such as ethylbenzene, 1H-indole, 3-methyl-1H-Indole, cetene, 3-hexadecene, 1-decene, 2,4,6-trimethyl-benzonitrile, and 2,5-dimethyl-pyrazine, persisted during room-temperature aging, but disappeared as the accelerated-aging period increased.



中文翻译:

亚临界水中脱水污泥产生的生物油的老化稳定性

在这项研究中,研究了在室温和加速老化条件下于80°C下历时6个月的脱水污水污泥的水热液化产生的生物油的稳定性。室温生物油样品的流动性,粘度或分子量没有观察到明显变化。加速老化的生物油样品保持其流动性长达1周,并且在老化1个月以上的样品中观察到粘度和分子量大幅增加。此外,室温老化样品的分解行为与新鲜生物油的分解行为非常相似,而随着加速老化的增加,86°C的低温分解峰逐渐降低并向高温方向移动时间。

更新日期:2020-08-06
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