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Elevated temperature molten salt corrosion study of SS304L austenitic boiler steel
Sādhanā ( IF 1.4 ) Pub Date : 2020-08-06 , DOI: 10.1007/s12046-020-01416-z
Sumit Mahajan , Rahul Chhibber

The aim of this study is to investigate the high-temperature corrosion behavior of 304L stainless steel in the environment of various molten salt mixtures in the temperature range of 550–850°C. Weight change measurement has been done and characterization of corroded specimen was carried out using XRD, SEM/EDS techniques. Findings indicate that high chloride concentration salts affect the corrosion resistance adversely. The protective behavior of Cr2O3 layer deteriorated and its passivation is hindered at higher temperature owing to the chlorination-oxidation process. Fe2O3 and (Fe, Cr)xOy were found to be the major phases in the corrosion product. The salts were found to significantly affect the corrosion of 304L stainless steel in the following order: K2SO4 + 60% NaCl > Na2SO4 + 50% NaCl > 40% K2SO4 + 40% Na2SO4 + 10% KCl + 10% NaCl > Na2SO4 + 60% V2O5 > Air.



中文翻译:

SS304L奥氏体锅炉钢的高温熔盐腐蚀研究

本研究的目的是研究550L至850°C温度范围内各种熔融盐混合物环境下304L不锈钢的高温腐蚀行为。已经进行了重量变化测量,并使用XRD,SEM / EDS技术对腐蚀样品进行了表征。结果表明,高氯化物浓度的盐会对耐腐蚀性产生不利影响。Cr 2 O 3层的保护行为由于氯化-氧化过程而变高,并且在较高的温度下其钝化受到阻碍。Fe 2 O 3和(Fe,Cr)x O y被发现是腐蚀产物的主要相。发现这些盐按以下顺序显着影响304L不锈钢的腐蚀:K 2 SO 4  + 60%NaCl> Na 2 SO 4  + 50%NaCl> 40%K 2 SO 4  + 40%Na 2 SO 4  + 10%KCl + 10%NaCl> Na 2 SO 4  + 60%V 2 O 5  >空气。

更新日期:2020-08-06
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