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Enhancement of microwave absorption bandwidth of MXene nanocomposites through macroscopic design.
Royal Society Open Science ( IF 2.9 ) Pub Date : 2020-08-05 , DOI: 10.1098/rsos.200456
Pritom J Bora 1 , T R Suresh Kumar 2, 3 , Daniel Q Tan 1
Affiliation  

MXene, the new family of two-dimensional materials having numerous nanoscale layers, is being considered as a novel microwave absorption material. However, MXene/functionalized MXene-loaded polymer nanocomposites exhibit narrow reflection loss (RL) bandwidth (RL less than or equal to −10 dB). In order to enhance the microwave absorption bandwidth of MXene hybrid-matrix materials, for the first time, macroscopic design approach is carried out for TiO2-Ti3C2Tx MXene and Fe3O4@TiO2-Ti3C2Tx MXene hybrids through simulation. The simulated results indicate that use of pyramidal meta structure of MXene can significantly tune the RL bandwidth. For optimized MXene hybrid-matrix materials pyramid pattern, the bandwidth enhances to 3–18 GHz. Experimental RL value well matched with the simulated RL. On the other hand, the optimized Fe3O4@TiO2-Ti3C2Tx hybrid exhibits two specific absorption bandwidths (minimum RL value - −47 dB). Compared with other two-dimensional nanocomposites such as graphene or Fe3O4-graphene, MXene hybrid-matrix materials show better microwave absorption bandwidth in macroscopic pattern.



中文翻译:

通过宏观设计提高MXene纳米复合材料的微波吸收带宽。

MXene是具有许多纳米级层的新型二维材料家族,被认为是一种新型的微波吸收材料。但是,MXene /官能化的MXene负载的聚合物纳米复合材料表现出较窄的反射损耗(RL)带宽(RL小于或等于-10 dB)。为了提高MXene杂化材料的微波吸收带宽,首次对TiO 2 -Ti 3 C 2 T x MXene和Fe 3 O 4 @TiO 2 -Ti 3 C 2进行了宏观设计。Ť XMXene通过仿真进行混合。仿真结果表明,使用MXene的金字塔元结构可以显着调整RL带宽。对于优化的MXene混合矩阵材料金字塔图案,带宽可提高到3–18 GHz。实验RL值与模拟RL很好地匹配。另一方面,优化的Fe 3 O 4 @TiO 2 -Ti 3 C 2 T x杂化物表现出两个特定的吸收带宽(最小RL值--47 dB)。与其他二维纳米复合材料(例如石墨烯或Fe 3 O 4石墨烯)相比,MXene杂化基质材料在宏观模式下显示出更好的微波吸收带宽。

更新日期:2020-08-05
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