Direct conversion of biomass derived L-rhamnose to 5-methylfurfural in water in high yield,Green Chemistry

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Direct conversion of biomass derived L-rhamnose to 5-methylfurfural in water in high yield
Green Chemistry ( IF 9.3 ) Pub Date : 2020-08-05 , DOI: 10.1039/d0gc02105a
Yunchao Feng _{1,

2,

3,

4} , Zheng Li _{5,

6,

7,

8} , Sishi Long _{1,

2,

3,

4} , Yong Sun _{1,

2,

3,

4,

9} , Xing Tang _{1,

2,

3,

4,

9} , Xianhai Zeng _{1,

2,

3,

4,

9} , Lu Lin _{1,

2,

3,

4,

9}

Affiliation

We report here that L-rhamnose, a less popular renewable and commercially available carbohydrate, can be used as a potential raw material to generate 5-methylfurfural (MF). In particular, nearly 100% yield of MF was achieved over 7 consecutive cycles in NaCl solution containing AlCl₃ within 30 min, thus providing an alternative and industrializable way for the production of the potential bio-platform compound MF.

中文翻译：

高产量将水中的生物质衍生的鼠李糖直接转化为5-甲基糠醛

我们在这里报告说，L-鼠李糖，一种不太流行的可再生和可商购的碳水化合物，可以用作产生5-甲基糠醛（MF）的潜在原料。特别地，在包含AlCl _3的NaCl溶液中，在30分钟内连续7个循环中，MF的收率接近100％，从而为潜在的生物平台化合物MF的生产提供了另一种可工业化的方法。

更新日期：2020-09-21

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