A bench-stable low-molecular-weight vinyl azide surrogate for a cascade reaction: facile access to novel N-vinyl-1,2,3-triazoles,Organic Chemistry Frontiers

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A bench-stable low-molecular-weight vinyl azide surrogate for a cascade reaction: facile access to novel N-vinyl-1,2,3-triazoles
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2020-08-04 , DOI: 10.1039/d0qo00714e
Zhenhua Liu _{1,

2,

3,

4,

5} , Lianxiao Wang _{1,

2,

3,

4,

5} , Tian Yu _{1,

2,

3,

4,

5} , Yanan Sun _{1,

2,

3,

4,

5} , Huimin Chen _{1,

2,

3,

4,

5} , Wen Gao _{1,

2,

3,

4,

5} , Bo Tang _{1,

2,

3,

4,

5}

Affiliation

A novel metal-catalyzed cascade reaction of a stable low-molecular-weight vinyl azide surrogate bearing a β-oxygen substituent in a general fashion was disclosed. The orderly insertion of S-/O-nucleophiles and alkynes, for the first time, successfully afforded a diverse range of sulfuryl-substituted N-vinyl-1,2,3-triazoles in good yields.

中文翻译：

稳定的低分子量叠氮化物用于级联反应的替代品：容易获得新型N-乙烯基-1,2,3-三唑

公开了一种新型的金属催化的稳定的，具有β-氧取代基的低分子量叠氮化物替代物的金属催化级联反应。S- / O-亲核试剂和炔的有序插入首次成功地以良好的收率提供了各种范围的硫基取代的N-乙烯基-1,2,3-三唑。

更新日期：2020-09-16

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