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Iron(III)-Mediated Rapid Radical-Type Three-Component Deuteration of Quinoxalinones With Olefins and NaBD4.
Frontiers in Chemistry ( IF 3.8 ) Pub Date : 2020-06-10 , DOI: 10.3389/fchem.2020.00606
Wanmei Li 1 , Heng Cai 1 , Lin Huang 1 , Lei He 1 , Yilan Zhang 1 , Jun Xu 1 , Pengfei Zhang 1
Affiliation  

Iron(III)-promoted rapid three-component deuteration of quinoxalinones with olefins and NaBD4 is reported for the first time, which provides a novel, economic, and efficient method for the rapid synthesis of deuterated quinoxalinones. In this transformation, a radical pathway is involved according to the results of control experiments.



中文翻译:


铁 (III) 介导的喹喔啉酮与烯烃和 NaBD4 的快速自由基型三组分氘化。



首次报道了铁(III)促进的喹喔啉酮与烯烃和NaBD 4的快速三组分氘化,为氘代喹喔啉酮的快速合成提供了一种新颖、经济、高效的方法。根据对照实验的结果,在这种转变中,涉及一种激进的途径。

更新日期:2020-08-04
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