Disulfide Promoted C−P Bond Cleavage of Phosphoramide: “P” Surrogates to Synthesize Phosphonates and Phosphinates,Advanced Synthesis & Catalysis

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Disulfide Promoted C−P Bond Cleavage of Phosphoramide: “P” Surrogates to Synthesize Phosphonates and Phosphinates
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2020-08-03 , DOI: 10.1002/adsc.202000511
Fei Hou ₁ , Xing‐Peng Du ₁ , Anwar I. Alduma ₁ , Zhi‐Feng Li ₂ , Cong‐De Huo ₁ , Xi‐Cun Wang ₁ , Xiao‐Feng Wu _{1,

3} , Zheng‐Jun Quan ₁

Affiliation

A metal‐free C−P bond cleavage reaction is described herein. Phosphoramides, a phosphine source, can react with alcohols to produce phosphonate and phosphinate derivatives in the presence of a disulfide. P−H₂, P‐alkyl, and P,P‐dialkyl phosphoramides can be used as substrates to obtain the corresponding pentavalent phosphine products.

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