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Iterative Suzuki-Miyaura Cross-coupling/Bromo-desilylation Reaction Sequences for the Assembly of Chemically Well-defined, Acyclic Oligopyrrole/Benzenoid Hybrids Embodying Mixed Modes of Connectivity.
Chemistry - An Asian Journal ( IF 4.1 ) Pub Date : 2020-08-04 , DOI: 10.1002/asia.202000740
BoRa Lee 1 , Anthony C Willis 1 , Jas S Ward 1 , Warren T Smith 2 , Ping Lan 3 , Martin G Banwell 1, 3
Affiliation  

Syntheses of a range of chemically well‐defined oligopyrrole/benzenoid hybrids are described using tandem Suzuki‐Miyaura cross‐coupling/bromo‐desilyation reaction sequences for linking borylated pyrroles, halogenated pyrroles and/or dibromobenzenes to one another. By such means, including iterative variants, a range of all α‐linked, all β‐linked oligopyrroles as well as certain combinations thereof have been assembled, some of them for the first time. The conductivities of iodine‐treated thin films formed from certain such systems have been determined.

中文翻译:

装配复杂连接方式的化学定义明确的无环低聚吡咯/苯甲杂化物组装的迭代Suzuki-Miyaura交叉偶联/溴代脱甲硅基反应序列。

使用串联的Suzuki-Miyaura交叉偶联/溴代脱甲硅反应顺序,描述了一系列化学定义明确的寡吡咯/苯并氮杂合物的合成,用于将硼酸化的吡咯,卤代吡咯和/或二溴代苯彼此连接。通过这样的方法,包括迭代变体,已经组装了所有α-连接的,β-连接的所有低聚吡咯以及它们的某些组合的范围,其中一些是第一次。已经确定了由某些此类系统形成的经过碘处理的薄膜的电导率。
更新日期:2020-10-02
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