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Structural, Optical and Decay Properties of Zinc(II) 8-Hydroxyquinoline and Its Thin Film
Journal of Electronic Materials ( IF 2.1 ) Pub Date : 2020-08-04 , DOI: 10.1007/s11664-020-08255-y
Deepshikha Painuly , R. Singhal , P. Kandwal , I. M. Nagpure

Zinc(II) 8-hydroxyquinoline (Znq2) green luminescent material and its blended thin film in a poly(methyl methacrylate) (PMMA) matrix have been prepared. XRD analysis confirms the formation of the compound and its presence in the PMMA blended thin film. The orbital molecular geometry, quantum chemical calculations and band gap energy of Znq2 phosphor have been confirmed from the DFT study. The morphology of the phosphor was shown by the SEM images. UV–Vis absorption, photoluminescence and decay analysis of zinc(II) 8-hydroxyquinoline phosphor confirms its suitability as a green emitter for organic light-emitting diodes. Uniform distribution of Znq2 powder in the PMMA matrix and its roughness was estimated by AFM analysis. Luminescence decay study was utilized to demonstrate its lifetime analysis by the time-correlated single-photon counting (TCSPC) system.



中文翻译:

锌(II)8-羟基喹啉及其薄膜的结构,光学和衰减特性

制备了锌(II)8-羟基喹啉(Znq 2)绿色发光材料及其在聚甲基丙烯酸甲酯(PMMA)基质中的混合薄膜。XRD分析证实了该化合物的形成及其在PMMA混合薄膜中的存在。DFT研究证实了Znq 2荧光粉的轨道分子几何结构,量子化学计算和带隙能。SEM图像显示了磷光体的形态。锌(II)8-羟基喹啉磷光体的UV-Vis吸收,光致发光和衰减分析证实了其适合作为有机发光二极管的绿色发射器。Znq 2的均匀分布通过AFM分析估计PMMA基体中的粉末及其粗糙度。通过时间相关的单光子计数(TCSPC)系统,利用发光衰减研究来证明其寿命分析。

更新日期:2020-08-04
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