Iron‐Catalyzed Cross‐Coupling Reactions for the Construction of Carbon‐Heteroatom Bonds,Asian Journal of Organic Chemistry

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Iron‐Catalyzed Cross‐Coupling Reactions for the Construction of Carbon‐Heteroatom Bonds
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-07-31 , DOI: 10.1002/ajoc.202000334
Juan Zhang ₁ , Siyu Wang ₁ , Yun Zhang ₁ , Zhang Feng _{1,

2}

Affiliation

Carbon‐heteroatom bonds are ubiquitous among pesticides, pharmaceutical agents, and natural products. In recent years, significant progress has been made in transition‐metal‐catalyzed carbon‐heteroatom bond formation. Especially, iron‐catalyzed reactions have become a focused area in organic chemistry owing to their advantages of low cost, economical and environmental benignity. This review intends to summarize the recent advances in the construction of carbon‐heteroatom bonds via cross‐coupling reactions using iron as a catalyst, including the formation of C−N, C−O, C−S, C−B, and C−Si bonds. A series of nucleophilic heteroatoms reagents, reaction classifications, and iron catalytic systems are discussed. In addition, some mechanistic studies have also been described.

中文翻译：

铁催化交叉偶联反应构建碳-杂原子键

碳-杂原子键在农药，药剂和天然产物中无处不在。近年来，在过渡金属催化的碳-杂原子键形成方面取得了重大进展。特别是，铁催化反应由于具有低成本，经济和环境友好的优势而成为有机化学领域的重点领域。这篇综述旨在总结通过使用铁作为催化剂的交叉偶联反应来构建碳-杂原子键的最新进展，包括形成CN，CO，CS，CB和C-。硅键。讨论了一系列亲核杂原子试剂，反应分类和铁催化体系。此外，还描述了一些机理研究。

更新日期：2020-07-31

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