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The Thermally Activated Distortion with Amplification Effect and related variant selection in red gold alloys
Acta Materialia ( IF 8.3 ) Pub Date : 2020-10-01 , DOI: 10.1016/j.actamat.2020.07.064
Margaux N.D. Larcher , Cyril Cayron , Andreas Blatter , Raphaëlle Soulignac , Roland E. Logé

Abstract Variant selection during the A1→L10 transformation in a polycrystalline red gold alloy close to equiatomic Au-Cu composition has been extensively studied by Electron Back Scattered Diffraction (EBSD) in our previous work. The use of a mathematical description of the lattice distortion and the maximal work criterion allowed us to quantify the degree of selection. With the same approach, we investigate here an interesting shape distortion effect, discovered twenty years ago in equiatomic AuCu-Ga. The shape distortion of thin samples placed in bending condition and then heat-treated under stress is studied in details. The singular shape memory effect and the remarkable distortion amplification, which we call TADA effect, are explored by monitoring the sample radius of curvature and the advancement of the transformation. The underlying mechanisms of variant selection are revealed by EBSD analysis across the samples. The experimental crystallographic variant selection distribution is compared with the expected profile calculated with the Euler-Bernoulli beam theory. The good agreement demonstrates that variant selection during the transformation is at the origin of the macroscopic distortion of red gold alloys. The TADA effect was found to occur when external stresses are released, and strongly depends on the stress at the initial stage of the transformation. This unusual effect is assumed to result from the persistence of variant selection throughout the transformation.

中文翻译:

红金合金中具有放大效应的热激活失真及相关变体选择

摘要 在我们之前的工作中,已经通过电子背散射衍射 (EBSD) 广泛研究了接近等原子 Au-Cu 组成的多晶红金合金中 A1→L10 转变过程中的变体选择。使用晶格畸变的数学描述和最大功标准使我们能够量化选择的程度。使用相同的方法,我们在这里研究了二十年前在等原子 AuCu-Ga 中发现的有趣的形状畸变效应。详细研究了在弯曲条件下放置然后在应力下热处理的薄样品的形状变形。通过监测样本曲率半径和变换的进展,探索奇异形状记忆效应和显着的失真放大,我们称之为 TADA 效应。通过跨样本的 EBSD 分析揭示了变异选择的潜在机制。将实验晶体变体选择分布与使用 Euler-Bernoulli 光束理论计算的预期轮廓进行比较。良好的一致性表明,转变过程中的变体选择是红金合金宏观畸变的根源。当外部应力释放时,发现 TADA 效应发生,并且强烈依赖于转变初始阶段的应力。这种不寻常的效果被认为是由于在整个转化过程中持续进行变体选择造成的。将实验晶体变体选择分布与使用 Euler-Bernoulli 光束理论计算的预期轮廓进行比较。良好的一致性表明,转变过程中的变体选择是红金合金宏观畸变的根源。发现 TADA 效应在外部应力释放时发生,并且强烈依赖于转变初始阶段的应力。这种不寻常的效果被认为是由于在整个转化过程中持续进行变体选择造成的。将实验晶体变体选择分布与使用 Euler-Bernoulli 光束理论计算的预期轮廓进行比较。良好的一致性表明,转变过程中的变体选择是红金合金宏观畸变的根源。发现 TADA 效应在外部应力释放时发生,并且强烈依赖于转变初始阶段的应力。这种不寻常的效果被认为是由于在整个转化过程中持续进行变体选择造成的。并且强烈依赖于转变初期的应力。这种不寻常的效果被认为是由于在整个转化过程中持续进行变体选择造成的。并且强烈依赖于转变初期的应力。这种不寻常的效果被认为是由于在整个转化过程中持续进行变体选择造成的。
更新日期:2020-10-01
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