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High-performance CrxFe2-xO3 mixed oxides for catalytic combustion of dichloromethane
Catalysis Communications ( IF 3.7 ) Pub Date : 2020-07-31 , DOI: 10.1016/j.catcom.2020.106126
Wei-Ping Du , Shuang Xu , Cen Tang , Ai-Ping Jia , Meng-Fei Luo , Ji-Qing Lu

A series of CrxFe2-xO3 mixed oxides were tested for catalytic combustion of dichloromethane. The best performance was obtained on a Cr0.8Fe1.2O3 catalyst (with a reaction rate of 3.11 mmol g−1 h−1 at 250 °C), which is higher than most of the results in literature. The reaction behavior was synergistically governed by the reducibility and surface acidity of the catalyst, which could be tuned by the compositions of Cr and Fe species in the mixed oxide. As a result, the Cr0.8Fe1.2O3 catalyst with an optimal combination of reducibility and surface acidity accounted for the best performance.



中文翻译:

用于二氯甲烷催化燃烧的高性能Cr x Fe 2-x O 3混合氧化物

测试了一系列Cr x Fe 2-x O 3混合氧化物对二氯甲烷的催化燃烧。在Cr 0.8 Fe 1.2 O 3催化剂上获得最佳性能(在250°C下的反应速率为3.11 mmol g -1  h -1),高于大多数文献结果。反应行为由催化剂的还原性和表面酸度协同控制,这可以通过混合氧化物中Cr和Fe种类的组成来调节。结果,Cr 0.8 Fe 1.2 O 3 具有最佳还原性和表面酸度组合的催化剂具有最佳性能。

更新日期:2020-08-05
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