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Nickel Catalyzed Olefin Oligomerization and Dimerization.
Chemical Reviews ( IF 51.4 ) Pub Date : 2020-07-29 , DOI: 10.1021/acs.chemrev.0c00076 H Olivier-Bourbigou 1 , P A R Breuil 1 , L Magna 1 , T Michel 1 , M Fernandez Espada Pastor 1 , D Delcroix 1
Chemical Reviews ( IF 51.4 ) Pub Date : 2020-07-29 , DOI: 10.1021/acs.chemrev.0c00076 H Olivier-Bourbigou 1 , P A R Breuil 1 , L Magna 1 , T Michel 1 , M Fernandez Espada Pastor 1 , D Delcroix 1
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Brought to life more than half a century ago and successfully applied for high-value petrochemical intermediates production, nickel-catalyzed olefin oligomerization is still a very dynamic topic, with many fundamental questions to address and industrial challenges to overcome. The unique and versatile reactivity of nickel enables the oligomerization of ethylene, propylene, and butenes into a wide range of oligomers that are highly sought-after in numerous fields to be controlled. Interestingly, both homogeneous and heterogeneous nickel catalysts have been scrutinized and employed to do this. This rare specificity encouraged us to interlink them in this review so as to open up opportunities for further catalyst development and innovation. An in-depth understanding of the reaction mechanisms in play is essential to being able to fine-tune the selectivity and achieve efficiency in the rational design of novel catalytic systems. This review thus provides a complete overview of the subject, compiling the main fundamental/industrial milestones and remaining challenges facing homogeneous/heterogeneous approaches as well as emerging catalytic concepts, with a focus on the last 10 years.
中文翻译：
镍催化的烯烃低聚和二聚。
镍催化的烯烃低聚反应早在半个多世纪前就已诞生并成功应用于高价值的石油化工中间体生产中，但它仍然是一个充满活力的话题，需要解决许多基本问题并克服工业挑战。镍独特且用途广泛的反应性使乙烯，丙烯和丁烯低聚为多种低聚物，这些低聚物在许多领域都受到控制。有趣的是，均相和非均相镍催化剂均已被仔细研究并用于此。这种罕见的特殊性鼓励我们在本综述中将它们相互联系，从而为进一步的催化剂开发和创新开辟机会。在新的催化体系的合理设计中，深入了解反应中的反应机理对于微调选择性和实现效率至关重要。因此，本次审查提供了对该主题的完整概述，汇总了主要的基本/工业里程碑以及同质/异质方法以及新兴的催化概念所面临的挑战，重点是最近十年。
更新日期：2020-08-12
中文翻译：
镍催化的烯烃低聚和二聚。
镍催化的烯烃低聚反应早在半个多世纪前就已诞生并成功应用于高价值的石油化工中间体生产中，但它仍然是一个充满活力的话题，需要解决许多基本问题并克服工业挑战。镍独特且用途广泛的反应性使乙烯，丙烯和丁烯低聚为多种低聚物，这些低聚物在许多领域都受到控制。有趣的是，均相和非均相镍催化剂均已被仔细研究并用于此。这种罕见的特殊性鼓励我们在本综述中将它们相互联系，从而为进一步的催化剂开发和创新开辟机会。在新的催化体系的合理设计中，深入了解反应中的反应机理对于微调选择性和实现效率至关重要。因此，本次审查提供了对该主题的完整概述，汇总了主要的基本/工业里程碑以及同质/异质方法以及新兴的催化概念所面临的挑战，重点是最近十年。
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