Front Cover Picture: Iridium(I) Complexes with Anionic N‐Heterocyclic Carbene Ligands as Catalysts for H/D Exchange in Nonpolar Media (Adv. Synth. Catal. 18/2020),Advanced Synthesis & Catalysis

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Front Cover Picture: Iridium(I) Complexes with Anionic N‐Heterocyclic Carbene Ligands as Catalysts for H/D Exchange in Nonpolar Media (Adv. Synth. Catal. 18/2020)
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2020-07-29 , DOI: 10.1002/adsc.202000673
Marvin Koneczny ₁ , Luong Phong Ho ₁ , Alexandre Nasr ₁ , Matthias Freytag ₁ , Peter G. Jones ₁ , Matthias Tamm ₁

Affiliation

The front cover picture, provided by Matthias Tamm and co‐workers and designed by Mailin Röder, illustrates a new class of stable iridium(I) complexes with N‐heterocyclic carbenes (NHC) bearing a weakly coordination anionic borate moiety. This piggyback B(C₆F₅)₃ unit affords neutrally charged iridium catalysts for efficient deuteration of various substrates with D₂ gas in nonpolar solvents. Details can be found in the full paper on pages 3857–3863 (M. Koneczny, L. P. Ho, A. Nasr, M. Freytag, P. G. Jones, M. Tamm, Adv. Synth. Catal. 2020, 362, 3857–3863; DOI: 10.1002/adsc.202000438).

中文翻译：

封面图片：铱（I）与阴离子N-杂环碳配体的络合物作为非极性介质中H / D交换的催化剂（Adv。Synth。Catal。18/2020）

所述前盖的画面，通过的Matthias的Tamm和同事提供和设计由Mailin罗德，示出了一类新的稳定铱（I）与N-杂环卡宾（NHC）带有弱配位阴离子硼酸部分的复合物。此背负式B（C ₆ F ₅）₃单元可提供带中性电荷的铱催化剂，用于在非极性溶剂中用D ₂气体对各种底物进行高效氘化。详情可在3857-3863（M. Koneczny，LP何A.纳斯尔，M. Freytag，PG琼斯，M.塔姆，网页的全文中找到。进阶合成器CATAL。2020，362，3857-3863; DOI：10.1002 / adsc.202000438）。

更新日期：2020-09-21

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