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Synthesis of Distally‐Bridged Chiral Resorcinarene Crowns
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2020-07-29 , DOI: 10.1002/ejoc.202000874
Daniel A. Tan 1 , Chiara Massera 2 , Matthew J. McIldowie 1 , Mauro Mocerino 1
Affiliation  

The synthesis and characterisation of twelve novel distally‐bridged chiral resorcinarene crowns is presented. The fascinating architecture of these partially‐enclosed chiral basket molecules is evident in the structures which have been determined by single‐crystal X‐ray crystallography. This work enables further exploration of these enantio‐pure chiral baskets as possible chiral resolving agents.
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中文翻译:

远桥手性间苯二甲烯冠的合成

介绍了十二个新颖的远端桥接手性间苯二甲烯基冠的合成和表征。这些部分封闭的手性篮子分子的迷人结构在单晶X射线晶体学确定的结构中显而易见。这项工作可以进一步探索这些对映纯的手性提篮作为可能的手性拆分剂。
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更新日期:2020-09-15
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