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Corrosion of carbon steel in CO2 saturated brine at elevated temperatures
Journal of Petroleum Science and Engineering Pub Date : 2020-07-29 , DOI: 10.1016/j.petrol.2020.107638
Rida Elgaddafi , Ramadan Ahmed , Subhash Shah

One of the main challenges in oil and gas wells is ensuring wellbore and casing integrity in a CO2 saturated brine environment. The integrity of a well casing relies on its mechanical properties and corrosion resistance to harsh downhole conditions. This paper discloses the results of a mathematical modeling study and experimental investigation conducted to understand the corrosion behavior of carbon steel (AISI 1045 Medium Carbon steel) in CO2 saturated brine.

Corrosion experiments were carried out at 0.83 MPa varying temperature and CO2 partial pressure (CPP). To prepare test fluid, 1 wt % NaCl was added to deionized water and thoroughly mixed. The Weight loss (WL) and Linear polarization resistance (LPR) techniques were employed for investigating corrosion. A comprehensive corrosion model is formulated to predict corrosion in a CO2 environment containing high-salt concentration.

Results indicate a strong impact of temperature on CO2 corrosion in brine environment. At low CPPs (PCO2 ≤ 0.41 MPa), the pick corrosion rate was noted at 43 °C. Furthermore, the influence of NaCl content on corrosion was strongly affected by CO2 concentration. The model is predominantly in agreement with existing corrosion measurements and it predicts the inhibiting effect of salt in CO2 corrosion.



中文翻译:

高温下碳钢在CO 2饱和盐水中的腐蚀

油气井的主要挑战之一是确保在CO 2饱和盐水环境中的井筒和套管完整性。井筒的完整性取决于其机械性能和对恶劣井下条件的耐腐蚀性。本文公开了数学模型研究和实验研究的结果,以了解碳钢(AISI 1045中碳钢)在CO 2饱和盐水中的腐蚀行为。

腐蚀实验是在0.83 MPa的变化温度和CO 2分压(CPP)下进行的。为了制备测试流体,将1重量%的NaCl加入去离子水中并充分混合。重量损失(WL)和线性极化电阻(LPR)技术用于研究腐蚀。建立了全面的腐蚀模型以预测在高盐浓度的CO 2环境中的腐蚀。

结果表明温度对盐水环境中CO 2腐蚀的强烈影响。在低的CPP(P CO2  ≤0.41兆帕),拾取腐蚀速率在43℃指出。此外,NaCl含量对腐蚀的影响受CO 2浓度的强烈影响。该模型主要与现有的腐蚀测量结果一致,并且可以预测盐对CO 2腐蚀的抑制作用。

更新日期:2020-07-29
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