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Fabrication and electrical characteristics of flash-sintered SiO 2 -doped ZnO-Bi 2 O 3 -MnO 2 varistors
Journal of Advanced Ceramics ( IF 16.9 ) Pub Date : 2020-07-29 , DOI: 10.1007/s40145-020-0404-7
Pai Peng , Yujun Deng , Jingpeng Niu , Liyi Shi , Yunzhu Mei , Sanming Du , Juan Liu , Dong Xu

The dense ZnO-Bi2O3-MnO2-xSiO2 (ZBMS) varistors for x = 0, 1, 2, 3 wt% were fabricated by flash sintering method under the low temperature of 850 °C within 2 min. The sample temperature was estimated by a black body radiation model in the flash sintering process. The crystalline phase assemblage, density, microstructure, and electrical characteristics of the flash-sintered ZBMS varistors with different SiO2-doped content were investigated. According to the XRD analysis, many secondary phases were detected due to the SiO2 doping. Meanwhile, the average grain size decrease with increasing SiO2-doped content. The improved nonlinear characteristics were obtained in SiO2-doped samples, which can be attributed to the ion migration and oxygen absorption induced by the doped SiO2. The flash-sintered ZBMS varistor ceramics for x = 2 wt% exhibited excellent comprehensive electrical properties, with the nonlinear coefficient of 24.5, the threshold voltage and leakage current of 385 V·mm−1 and 11.8 µA, respectively.



中文翻译:

SiO 2掺杂ZnO-Bi 2 O 3 -MnO 2压敏烧结体的制备及电学特性

通过闪蒸烧结法在2分钟内于850°C的低温下制造了x = 0、1、2、3 wt%的致密ZnO-Bi 2 O 3 -MnO 2 - x SiO 2(ZBMS)压敏电阻。样品温度是通过黑体辐射模型在快速烧结过程中估算的。研究了不同SiO 2掺杂含量的ZBMS压敏烧结压敏电阻的晶相组成,密度,微观结构和电学特性。根据XRD分析,由于SiO 2掺杂,检测到许多次级相。同时,平均晶粒尺寸随着SiO 2的增加而减小掺杂的内容。掺杂SiO 2的样品具有改善的非线性特性,这可以归因于掺杂SiO 2引起的离子迁移和氧吸收。x = 2 wt%的ZBMS压敏烧结陶瓷表现出优异的综合电性能,其非线性系数为24.5,阈值电压和漏电流分别为385 V·mm -1和11.8 µA。

更新日期:2020-07-29
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