ABSTRACT A novel three-component reaction between isocyanides, isothiocyanates, and oxiranes has been developed. An array of substituted oxathianes have been obtained in acceptable to good yields. The reaction product could be modulated using Bu3P or TBPAc as an organo-catalyst. This work offers an opportunity for the further implementation of isocyanides in library design. GRAPHICAL ABSTRACT

中文翻译：

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从异氰化物、异硫氰酸酯和环氧乙烷有机催化合成氧杂

摘要 已开发出异氰化物、异硫氰酸酯和环氧乙烷之间的新型三组分反应。已经以可接受的良好收率获得了一系列取代的氧杂环己烷。可以使用 Bu3P 或 TBPAc 作为有机催化剂调节反应产物。这项工作为在图书馆设计中进一步实施异氰化物提供了机会。图形概要