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Iso-conversional study of crystallization activation energy of amorphous-crystallization transformation for Se79Te20Pb1 glass using non-isothermal differential scanning calorimetry technique
Indian Journal of Pure & Applied Physics ( IF 0.6 ) Pub Date : 2020-03-20 Priyanka Vashist, Balbir Singh Patial, Anjali, S K Tripathi, Nagesh Thakur
Indian Journal of Pure & Applied Physics ( IF 0.6 ) Pub Date : 2020-03-20 Priyanka Vashist, Balbir Singh Patial, Anjali, S K Tripathi, Nagesh Thakur
The ternary Se79Te20Pb1 chalcogenide glass is prepared using melt quenching technique. Differential scanning calorimetry technique (DSC) is used to investigate the kinetics of crystallization of amorphous-crystallization (a-c) phase transformation under non-isothermal conditions at three different heating rates; 5, 10 and 15° C min-1. The variation of crystallized activation energy (Ec) with crystallized fraction (ϰ) and hence, with temperature (T) is investigated using five iso-conversional methods namely KAS, OFW, Friedman, Tang and Chen and Starink. It is found that Ec is not constant but vary with ϰ as well as T. Thus, the iso-conversional analysis of investigated glass indicates that the assumption of constant Ec is not appropriate.
中文翻译:
非等温差示扫描量热法研究Se79Te20Pb1玻璃非晶-晶化转变的晶化活化能
采用熔融淬火技术制备了三元Se 79 Te 20 Pb 1硫族化物玻璃。差示扫描量热技术(DSC)用于研究非等温条件下三种不同加热速率下非晶-结晶(ac)相变的结晶动力学。5、10和15°C min -1。结晶活化能(的变化ë Ç)与结晶级分(κ),因此,随着温度(Ť)是使用五个异conversional方法即KAS,OFW,弗里德曼,汤和Chen和Starink调查。发现E c不是常数,而是随κ以及Ť。因此,对研究玻璃的等转换分析表明,常数E c的假设是不合适的。
更新日期:2020-03-20
中文翻译:
非等温差示扫描量热法研究Se79Te20Pb1玻璃非晶-晶化转变的晶化活化能
采用熔融淬火技术制备了三元Se 79 Te 20 Pb 1硫族化物玻璃。差示扫描量热技术(DSC)用于研究非等温条件下三种不同加热速率下非晶-结晶(ac)相变的结晶动力学。5、10和15°C min -1。结晶活化能(的变化ë Ç)与结晶级分(κ),因此,随着温度(Ť)是使用五个异conversional方法即KAS,OFW,弗里德曼,汤和Chen和Starink调查。发现E c不是常数,而是随κ以及Ť。因此,对研究玻璃的等转换分析表明,常数E c的假设是不合适的。