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From terpenes to sustainable and functional polymers
Polymer Chemistry ( IF 4.1 ) Pub Date : 2020-07-27 , DOI: 10.1039/d0py00817f Francesco Della Monica 1, 2, 3, 4 , Arjan W. Kleij 1, 2, 3, 4, 5
Polymer Chemistry ( IF 4.1 ) Pub Date : 2020-07-27 , DOI: 10.1039/d0py00817f Francesco Della Monica 1, 2, 3, 4 , Arjan W. Kleij 1, 2, 3, 4, 5
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Our dependence on fossil-fuel based raw materials and alarming plastics accumulation in the environment has inspired many scientists to design and implement more sustainable approaches for polymer synthesis. The identification and assessment of new and renewable biobased monomers has become a major topic of interest en route to a circular economy. In this respect, terpenes and terpenoid scaffolds have attracted much attention due to their ubiquitous nature and high functionality. This minireview uncovers recent advancements in the synthesis of terpene-based polymers, and specifically discusses the formation of terpene-derived polycarbonates, polyesters, polyurethanes and polyamides. The potential of these polymers in post-synthetic curing and modifications is also highlighted to illustrate the opportunities that exist to develop new polymer formulations beyond bench scale.
中文翻译：
从萜烯到可持续的功能性聚合物
我们对基于化石燃料的原材料的依赖以及令人震惊的塑料在环境中的积累，激发了许多科学家设计和实施更可持续的聚合物合成方法。新型和可再生生物基单体的鉴定和评估已成为途中关注的主要话题循环经济。在这方面，萜烯和萜类支架因其普遍存在的性质和高功能性而引起了人们的广泛关注。这份小型综述揭示了萜烯基聚合物合成的最新进展，并特别讨论了萜烯衍生的聚碳酸酯，聚酯，聚氨酯和聚酰胺的形成。还强调了这些聚合物在合成后固化和改性中的潜力，以说明开发超出台式规模的新聚合物配方的机会。
更新日期：2020-08-18
中文翻译：
从萜烯到可持续的功能性聚合物
我们对基于化石燃料的原材料的依赖以及令人震惊的塑料在环境中的积累，激发了许多科学家设计和实施更可持续的聚合物合成方法。新型和可再生生物基单体的鉴定和评估已成为途中关注的主要话题循环经济。在这方面，萜烯和萜类支架因其普遍存在的性质和高功能性而引起了人们的广泛关注。这份小型综述揭示了萜烯基聚合物合成的最新进展，并特别讨论了萜烯衍生的聚碳酸酯，聚酯，聚氨酯和聚酰胺的形成。还强调了这些聚合物在合成后固化和改性中的潜力，以说明开发超出台式规模的新聚合物配方的机会。
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