Journal of Organometallic Chemistry ( IF 2.1 ) Pub Date : 2020-07-26 , DOI: 10.1016/j.jorganchem.2020.121418 Lincoln Dkhar , Merrily Sawkmie , Agustine Lamin Ka-Ot , Santa Ram Joshi , Werner Kaminsky , Mohan Rao Kollipara
A series of cationic complexes [(Cp/Ind)Ru(к2(SS)-L)(PPh3)]PF6 (1–6) are obtained by the reaction of [CpRu(PPh3)2Cl] or [(Ind)Ru(PPh3)2Cl] (Cp = η5-C5H5, Ind = η5-C9H7) with respective dithione derivatives 1,2-di(piperidin-1-yl)ethane-1,2-dithione (L1), 1,2-dimorpholinoethane-1,2-dithione (L2) and 1,2-dithiomorpholinoethane-1,2-dithione (L3). All the compounds are characterized using spectroscopic techniques. The molecular structures of complexes 1, 2 and 4 are established by single-crystal X-ray diffraction studies. Antimicrobial studies were tested against three strains of bacterial microorganisms Staphylococcus aureus (gram + ve), Bacillus subtilis (gram + ve), Klebsiella pneumoniae (gram -ve) and one strain of fungal microorganism Candida albicans.
中文翻译:
含二硫酮衍生物的Cp和茚基钌络合物:合成,抗菌和抗真菌研究
一系列阳离子络合物的[(CP /茚基)钌(к 2 (SS) -L)(PPH 3)] PF 6(1 - 6)通过[CPRU(PPH反应得到3)2 CL]或[ (茚基)的Ru(PPH 3)2 CL](CP =η 5 -C 5 H ^ 5,工业=η 5 -C 9 ħ 7)与相应的二硫酮衍生物1,2-二(哌啶-1-基)乙烷1,2-二硫酮(L1),1,2-二吗啉代乙烷-1,2-二硫酮(L2)和1,2-二硫吗啉代乙烷-1,2-二硫酮(L3)。所有化合物均使用光谱技术表征。配合物的分子结构1,2和4是通过单晶X射线衍射研究确定。对三株细菌性金黄色葡萄球菌(克+ ve),枯草芽孢杆菌(克+ ve),肺炎克雷伯菌(克-ve)和一株真菌白色念珠菌进行了抗菌研究。