A new organically templated uranyl molybdate [C₃H₉NH⁺]₄[(UO₂)₃(MoO₄)₅] was prepared by a hydrothermal method at 220 °C. The compound is monoclinic, Сс, a = 16.768(6), b = 20.553(8), c = 11.897(4) Å, β = 108.195(7), V = 3895(2) ų, R₁ = 0.05. The crystal structure is based upon [(UO₂)₃(MoO₄)₅]⁴⁻ uranyl molybdate layers. The isopropylammonium cations are located in the interlayer. The layers in the structure of [C₃H₉NH⁺]₄[(UO₂)₃(MoO₄)₅] are considered as modular architectures. Topological analysis of layers with UO₂:TO₄ ratio of 3:5 (T^VI = S, Cr, Se, Mo) was performed. Modular description is employed to elucidate the relationships between different structural topologies of [(UO₂)₃(TO₄)₅]⁴⁻ layers and inorganic uranyl-based nanotubules. The possible existence of uranyl molybdate nanotubules is discussed.

中文翻译：

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基于矿物相关模块单元的有机模板化层状钼酸铀酯[C3H9NH +] 4 [（UO2）3（MoO4）5]

通过水热法在220℃下制备了新的有机模板化的钼酸铀酰[C ₃ H ₉ NH ⁺ ] ₄ [（UO ₂）₃（MoO ₄）₅ ]。该化合物是单斜晶系，Сс，一个= 16.768（6），b = 20.553（8），C ^ = 11.897（4），β= 108.195（7），V = 3895（2）埃³，- [R ₁ = 0.05。晶体结构基于[（UO ₂）₃（MoO ₄）₅ ] ^4-钼酸铀酰层。异丙基铵阳离子位于中间层中。[C ₃ H ₉ NH ⁺ ] ₄ [（UO ₂）₃（MoO ₄）₅ ]的结构中的层被视为模块化体系结构。进行具有3：5（T ^VI = S，Cr，Se，Mo）的UO ₂：T O ₄比的层的拓扑分析。采用模块描述来阐明[（UO ₂）₃（T O ₄）_5的不同结构拓扑之间的关系] ^4-层和基于无机铀酰的纳米管。讨论了钼酸铀酰纳米管的可能存在。