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High-flux neutron irradiation of boron trioxide analyzed with Raman and FTIR spectroscopy
International Journal of Modern Physics B ( IF 1.7 ) Pub Date : 2020-07-06 , DOI: 10.1142/s021797922050160x
Matlab N. Mirzayev 1, 2
Affiliation  

Boron oxide nanopowder is widely used in the production of special glasses and nuclear technology. This paper reports on the optical properties and investigates the formation of new bonds on the structure of nanoboron oxide. In this work, high purity boron oxide samples were irradiated using a energy upto 1 MeV fast neutrons with fluences in the range of [Formula: see text], [Formula: see text], [Formula: see text], [Formula: see text] and the neutron flux [Formula: see text] at the room-temperature. Optical properts were determined using Raman spectrum analysis and spectroscopy Fourier transform infrared (FTIR) spectroscopy. FTIR and Raman spectrum analysis were used to explain the chemical bonds and functional groups of nanoboron oxide samples before and after neutron irradiation. When the irradation fluence on [Formula: see text] was increased upto [Formula: see text] it resulted in the formation of a new functional groups [Formula: see text]. From the Raman analysis, the [Formula: see text] was observed to start amorphization after neutron irradiation.

中文翻译:

用拉曼和 FTIR 光谱分析三氧化硼的高通量中子辐照

氧化硼纳米粉体广泛用于特种玻璃的生产和核技术。本文报道了光学性质并研究了纳米氧化硼结构上新键的形成。在这项工作中,使用能量高达 1 MeV 的快中子辐照高纯度氧化硼样品,其注量范围为 [公式:见正文]、[公式:见正文]、[公式:见正文]、[公式:见文本]和室温下的中子通量[公式:见文本]。使用拉曼光谱分析和光谱傅里叶变换红外 (FTIR) 光谱测定光学性质。FTIR和拉曼光谱分析用于解释中子辐照前后纳米氧化硼样品的化学键和官能团。当辐照能量对 [公式:见正文]增加到[公式:见正文]它导致形成新的官能团[公式:见正文]。根据拉曼分析,观察到[公式:见正文]在中子照射后开始非晶化。
更新日期:2020-07-06
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