Complexes featuring metal–silicon bonds play a key role in many catalytic and stoichiometric transformations. As such, it is important to understand the underlying electronic structures of such units and the reactivity patterns they engender, which in many cases differ substantially from well-known patterns for metal–carbon bonds. This review seeks to provide a framework for understanding reactivity of metal/organosilicon units, focusing specifically on considerations for catalysis, similarities and differences between M–C and M–Si chemistry, and possibilities for M/Si cooperative catalysis.

中文翻译：

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金属/有机硅配合物：结构，反应性和催化因素

具有金属-硅键的配合物在许多催化和化学计量转化中起着关键作用。因此，重要的是要了解此类单元的基本电子结构及其产生的反应模式，在许多情况下，这些模式与众所周知的金属-碳键模式大不相同。这篇综述旨在为理解金属/有机硅单元的反应性提供一个框架，特别关注催化方面的考虑，MC和M-Si化学之间的异同以及M / Si协同催化的可能性。