Saturated NHC Derived Dichalcogen Dications,Zeitschrift für anorganische und allgemeine Chemie

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Saturated NHC Derived Dichalcogen Dications
Zeitschrift für anorganische und allgemeine Chemie ( IF 1.1 ) Pub Date : 2020-06-23 , DOI: 10.1002/zaac.202000189
Dennis Rottschäfer ₁ , Désirée E. Fuhs ₁ , Beate Neumann ₁ , Hans‐Georg Stammler ₁ , Rajendra S. Ghadwal ₁

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Herein, the synthesis and characterization of dicationic dichalcogenide compounds [(SIPr)E]2(OTf)2 (3a-E) (E = S, Se, Te) based on a saturated N-heterocyclic carbene (NHC), SIPr [SIPr = C{N(Dipp)CH2}2, Dipp = 2,6-iPr2C6H3] are reported. Treatment of SIPr (1a) with elemental chalcogens affords the heavier ketone deriva-

中文翻译：

饱和 NHC 衍生二硫属元素离子

在此，基于饱和 N-杂环卡宾 (NHC)、SIPr [SIPr] 的双阳离子二硫属化物化合物 [(SIPr)E]2(OTf)2 (3a-E) (E = S, Se, Te) 的合成和表征= C{N(Dipp)CH2}2, Dipp = 2,6-iPr2C6H3]。用元素硫属元素处理 SIPr (1a) 可得到更重的酮衍生物

更新日期：2020-06-23

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