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Bis-Organosilicon based receptor for detection of Hg2+ ions: Low detection limit and excellent selectivity
Journal of Organometallic Chemistry ( IF 2.1 ) Pub Date : 2020-07-24 , DOI: 10.1016/j.jorganchem.2020.121458
Gurjaspreet Singh , Pinky Satija , Akshpreet Singh , Kavita Chowdhary , Geetika Sharma , Mohit , Shilpy , Jandeep Singh , Jasbhinder Singh

Mercury Contamination represents a major environmental and health concern for which new eco-friendly solutions are desired. Azide–alkyne cycloaddition and Claisen Schmidt reaction were attempted to trigger a flavanone based bis-siloxyl hybrid materials. The synthesized bis-organosilicon compound was used as receptor for recognition of Hg (II) ions in semi aqueous medium. The presence of silicon makes the receptor impetus and has benefits in the field of nanochemistry. All the final compounds were recognized by spectroscopic techniques like IR, NMR and further corroborate by mass spectrometry.



中文翻译:

基于双有机硅的受体可检测Hg 2+离子:低检测限和出色的选择性

汞污染代表着对环境和健康的关注,因此需要新的环保解决方案。尝试使用叠氮化物-炔烃环加成反应和Claisen Schmidt反应来引发基于黄烷酮的双甲硅烷氧基杂化材料。合成的双有机硅化合物用作受体,用于识别半水介质中的Hg(II)离子。硅的存在推动了受体的发展,并在纳米化学领域中受益。所有最终化合物均通过光谱技术(例如IR,NMR)识别,并通过质谱进一步证实。

更新日期:2020-07-30
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