Talanta ( IF 5.6 ) Pub Date : 2020-07-22 , DOI: 10.1016/j.talanta.2020.121430 Yi Fen Xie 1 , Yong Jian Jiang 2 , Hong Yan Zou 1 , Jian Wang 1 , Cheng Zhi Huang 3
A simple and fast method for copper ions (Cu2+) and silver ions (Ag+) detection was established with cadmium telluride quantum dots (CdTe QDs) as fluorescent probes. In the presence of Cu2+ or Ag+, the fluorescence intensity of TGA-CdTe QD can be significantly quenched, which fitted a linear relationship between the fluorescence quenching degree (F0–F)/F0 and the concentration of metal ions. In this work, the lowest detected concentration for Cu2+ and Ag+ was 35.0 nM and 25.3 nM, respectively. In addition, the differentiation of Cu2+ and Ag+ at different concentrations was realized with the principal component analysis (PCA). Furthermore, Cu2+ was successfully detected in body fluids. This method provides a good potential for copper ions and silver ions detection with simplicity, rapidity, and excellent selectivity.
中文翻译:
基于无标记量子点的铜离子和银离子的区分。
以碲化镉量子点(CdTe QDs)为荧光探针,建立了一种简便,快速的铜离子(Cu 2+)和银离子(Ag +)检测方法。在Cu 2+或Ag +的存在下,TGA-CdTe QD的荧光强度可以显着猝灭,这与荧光猝灭度(F 0 - F)/ F 0和金属离子的浓度呈线性关系。在这项工作中,Cu 2+和Ag +的最低检测浓度分别为35.0 nM和25.3 nM。另外,Cu 2+和Ag +的分化主成分分析(PCA)可以实现不同浓度的化合物。此外,在体液中已成功检测到Cu 2+。该方法具有简便,快速和出色的选择性,为铜离子和银离子检测提供了良好的潜力。