当前位置: X-MOL 学术J. Iran. Chem. Soc. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Facile synthesis of Ce-doped SnO 2 nanoparticles with enhanced performance for photocatalytic degradation of organic dye
Journal of the Iranian Chemical Society ( IF 2.2 ) Pub Date : 2020-07-21 , DOI: 10.1007/s13738-020-02000-2
Ameer Baig Ali Baig , Vadamalar Rathinam , Jayanthi Palaninathan

Cerium (Ce)-doped tin dioxide (SnO2) nanoparticles (NPs) have been prepared by a facile hydrothermal coprecipitation route for photocatalytic decomposition of methyl orange (MO) dye. The as-obtained NPs were characterized using different physical methods. X-ray diffraction (XRD) analysis found a rutile-phase-like crystalline structure. X-ray photoelectron spectroscopy (XPS) revealed specific energies of 486.2 eV for Sn 3d3/2 and 497.4 eV for Sn 3d5/2 and confirmed an oxidation state of Sn4+. With increasing Ce concentration (from 0% to 2% and 4%), the optical bandgap energy of the SnO2 NPs reduced (3.4–3.1 eV), resulting in a red-shift that enhanced their photocatalytic activity. The 4% Ce:SnO2 NPs exhibited superior photodegradation performance against MO organic dye, achieving 94.5% decomposition in 100 min under exposure to ultraviolet–visible (UV–Vis) light. Indeed, the photocatalytic efficiency of the 4% Ce:SnO2 NPs was 4.9- and 2.44-fold higher than that of the bare SnO2 and 2% Ce:SnO2 NPs, respectively. This outstanding photodegradation efficacy of the as-obtained 4% Ce:SnO2 NPs was due to the effective doping of Ce into the SnO2 lattice, thus preventing the recombination and allowing the effective separation/migration of photoexcited charges (e/h+). Furthermore, improved antibacterial activity against two bacteria was clearly observed when adding Ce dopant to the SnO2 NPs.



中文翻译:

铈掺杂SnO 2纳米粒子的光催化降解有机染料性能增强

铈(Ce)掺杂的二氧化锡(SnO 2)纳米颗粒(NPs)已通过一种简便的水热共沉淀途径制备,用于光催化分解甲基橙(MO)染料。使用不同的物理方法对获得的NP进行表征。X射线衍射(XRD)分析发现金红石相状晶体结构。X射线光电子能谱(XPS)显示,Sn 3 d 3/2的比能为486.2 eV,Sn 3 d 5/2的比能为497.4 eV,并证实了Sn 4+的氧化态。随着Ce浓度的增加(从0%到2%和4%),SnO 2的光学带隙能量NP减少(3.4–3.1 eV),导致红移,从而增强了它们的光催化活性。4%的Ce:SnO 2 NPs对MO有机染料表现出优异的光降解性能,在暴露于紫外可见光(UV-Vis)的情况下,在100分钟内可实现94.5%的分解。实际上,4%Ce:SnO 2 NP的光催化效率分别比裸露SnO 2和2%Ce:SnO 2 NP的光催化效率分别高4.9和2.44倍。如此获得的4%Ce:SnO 2 NP的这种出色的光降解功效是由于将Ce有效掺杂到SnO 2晶格中,从而防止了重组,并允许有效分离/迁移光激发电荷(e- / h +)。此外,当将Ce掺杂剂添加到SnO 2 NP中时,清楚地观察到针对两种细菌的​​改善的抗菌活性。

更新日期:2020-07-21
down
wechat
bug