The densities and dynamic viscosities of three binary liquid mixtures of tricyclo [5.2.1.02,6] deca-3,8-diene(endo-DCPD) with ethanol, 2-propanol and 1-pentanol at different temperatures (293.15, 303.15 and 313.15) K and atmospheric pressure were measured over the entire compositional range. The excess molar volume, viscosity deviation and excess Gibbs energy for activation of the viscous flow of mixtures were calculated and adjusted by the Redlich–Kister equation. The excess molar volume data were correlated using Prigogine–Flory–Patterson (PFP) theory. Five typical semi-empirical correlations with one and two interaction parameters and predictive models UNIFAC Dortmund_VISCO (Universal Functional Activity Coefficients modified by Dortmund-Viscosity) and ASOG_VISCO (Analytical Solution Group-Viscosity) with newly estimated interaction parameters were used to correlate viscosity. In addition, excess Gibbs free energy results were estimated using local composition concept and group contribution models. All of these results provide important information on the research and application of high-density jet fuel with green fuel as additives.

中文翻译：

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含醇类添加剂的高密度喷气燃料热物理性能研究

三环 [5.2.1.02,6] deca-3,8-diene(endo-DCPD)与乙醇、2-丙醇和1-戊醇的三种二元液体混合物在不同温度（293.15、303.15和313.15）下的密度和动态粘度) K 和大气压是在整个组成范围内测量的。用于激活混合物粘性流动的过量摩尔体积、粘度偏差和过量吉布斯能量通过 Redlich-Kister 方程计算和调整。使用 Prigogine-Flory-Patterson (PFP​​) 理论关联过量摩尔体积数据。五个典型的半经验相关性与一个和两个相互作用参数和预测模型 UNIFAC Dortmund_VISCO（由多特蒙德粘度修改的通用功能活性系数）和 ASOG_VISCO（分析解决方案组粘度）与新估计的相互作用参数用于关联粘度。此外，过量的吉布斯自由能结果是使用局部组成概念和群贡献模型估计的。这些结果为以绿色燃料为添加剂的高密度喷气燃料的研究和应用提供了重要信息。