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New 11-vertex osmacarborane 1,1-(PPh3)2-1-H-3-O(CH2)4-isonido-1,2,4-OsC2B8H9
Russian Chemical Bulletin ( IF 1.7 ) Pub Date : 2020-06-01 , DOI: 10.1007/s11172-020-2888-2
E. V. Balagurova , I. A. Godovikov , I. T. Chizhevsky

Hydride-containing 1,1-(PPh3)2-1-H-3-O(CH2)4-isonido-1,2,4-OsC2B8H9 osmacarborane bearing a charge-compensated ligand was synthesized via a reaction of the deprotonated form of medium non-icosahedral 5,6-nido-C2B8H12 carborane with (PPh3)3OsCl2 in a THF solution. The structure of this complex was assigned using 1H, 11B/11B{1H}, and 31P{1H} NMR spectroscopy.

中文翻译:

新的 11 顶点锇碳硼烷 1,1-(PPh3)2-1-H-3-O(CH2)4-isonido-1,2,4-OsC2B8H9

带有电荷补偿配体的含氢化物 1,1-(PPh3)2-1-H-3-O(CH2)4-isonido-1,2,4-OsC2B8H9 锇碳硼烷是通过去质子化形式的中等非二十面体 5,6-nido-C2B8H12 碳硼烷与 (PPh3)3OsCl2 在 THF 溶液中。使用 1H、11B/11B{1H} 和 31P{1H} NMR 光谱确定了该复合物的结构。
更新日期:2020-06-01
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