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A Long-Sought Reactivity of a Sodium Hydride
Trends in Chemistry ( IF 14.0 ) Pub Date : 2020-07-18 , DOI: 10.1016/j.trechm.2020.07.001 Paweł J. Czerwiński , Bartłomiej Furman
中文翻译:
氢化钠的长期反应
更新日期:2020-07-18
Trends in Chemistry ( IF 14.0 ) Pub Date : 2020-07-18 , DOI: 10.1016/j.trechm.2020.07.001 Paweł J. Czerwiński , Bartłomiej Furman
Hydride from sodium hydride acts as a base and not as a nucleophile, due to its small size and high charge density. However, recent research has found that a sodium hydride–sodium iodide composite can be a unique hydride donor in the challenging partial reduction of inert amides to imines.
中文翻译:
氢化钠的长期反应
由于氢化钠的小尺寸和高电荷密度,其氢化物起碱的作用而不是亲核试剂的作用。但是,最近的研究发现,氢化钠-碘化钠复合物在将惰性酰胺部分还原为亚胺方面具有挑战性,可以成为独特的氢化物供体。