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Effect of cerium oxide on preparation of high-density sintered magnesia from crystal magnesite
Journal of Materials Research and Technology ( IF 6.2 ) Pub Date : 2020-07-18 , DOI: 10.1016/j.jmrt.2020.06.045
Endong Jin , Jingkun Yu , Tianpeng Wen , Chen Tian , Zhaoyang Liu , Beiyue Ma , Lei Yuan

Sintered MgO was prepared by using MgO powder with different particle sizes by calcination of by crystal magnesite as the raw material and CeO2 powder as an additive. In addition, the effect of the CeO2 addition on the performance of the sintered MgO was investigated. The results showed that (i) the densification of the sintered MgO with a small amount of CeO2 addition appreciably promoted, (ii) the maximum bulk density reached 3.48 g cm−3, and (iii) the apparent porosity was 0.35%. In the sintering process, the Ca2+ could approach into CeO2 lattices, forming O2− vacancy at CeO2 grains, which resulted in promoting the growth of CeO2 grains filling the pores between the MgO grains, and enhanced the densification of sintered MgO. In addition, the solid solution reaction limited the formation of silicate phase in MgO, improving the bonding degree between the MgO grains.



中文翻译:

氧化铈对菱镁矿晶体制备高密度烧结氧化镁的影响

通过以菱镁矿晶体为原料,以CeO 2粉末为煅烧剂,使用粒径不同的MgO粉末来制备烧结MgO 。另外,研究了CeO 2添加对烧结的MgO的性能的影响。结果表明:(i)添加少量CeO 2的烧结MgO的致密化得到明显促进,(ii)最大堆积密度达到3.48g cm -3,并且(iii)表观孔隙率为0.35%。在烧结过程中,Ca 2+可以进入CeO 2晶格,在CeO 2晶粒上形成O 2-空位,从而促进了CeO的生长2个晶粒填充了MgO晶粒之间的孔,并增强了烧结MgO的致密化。另外,固溶反应限制了MgO中硅酸盐相的形成,从而改善了MgO晶粒之间的键合度。

更新日期:2020-07-18
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