当前位置：
X-MOL 学术
›
Adv. Synth. Catal.
›
论文详情
Our official English website, www.x-mol.net, welcomes your
feedback! (Note: you will need to create a separate account there.)
Hydroboration of Enynes and Mechanistic Insights
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2020-07-16 , DOI: 10.1002/adsc.202000603 Lujia Mao 1 , Shubhankar Kumar Bose 2
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2020-07-16 , DOI: 10.1002/adsc.202000603 Lujia Mao 1 , Shubhankar Kumar Bose 2
Affiliation
|
Organoboron compounds have found broad applications in the construction of novel C−C, C−O, and C−N bonds via transition metal‐catalyzed reactions. The hydroboration of C−C multiple bonds is one of the most important methodologies to introduce the boron atom into the organic skeleton. Traditionally, boranes were employed in the hydroboration of enynes under transition metal‐free conditions. When precious metal catalysts, such as palladium and rhodium were employed in the reactions, the scope of the hydroboration, as well as the regio‐ and stereoselectivity, was improved. The asymmetric hydroboration of enynes was also achieved via Pd‐catalyzed reactions. In recent years, the non‐precious 3d‐metal catalysts, such as iron, cobalt, nickel and copper were employed in the hydroboration of enynes, especially in the enantioselective reactions. In this review, we have looked into the hydroboration of enynes as well as their mechanisms.
中文翻译：
炔烃的硼氢化和机理研究
通过过渡金属催化的反应，有机硼化合物已在新型C–C，C–O和C–N键的构建中得到广泛应用。C-C多重键的硼氢化是将硼原子引入有机骨架的最重要方法之一。传统上，在无过渡金属的条件下，硼烷用于烯炔的硼氢化。当在反应中使用钯和铑等贵金属催化剂时，硼氢化反应的范围以及区域和立体选择性都得到了改善。烯炔的不对称硼氢化也可以通过钯催化的反应。近年来，在炔烃的硼氢化反应中，特别是在对映选择性反应中，使用了非贵重的3d金属催化剂，如铁，钴，镍和铜。在这篇综述中，我们研究了炔烃的硼氢化及其机理。
更新日期：2020-07-16
中文翻译：
炔烃的硼氢化和机理研究
通过过渡金属催化的反应，有机硼化合物已在新型C–C，C–O和C–N键的构建中得到广泛应用。C-C多重键的硼氢化是将硼原子引入有机骨架的最重要方法之一。传统上，在无过渡金属的条件下，硼烷用于烯炔的硼氢化。当在反应中使用钯和铑等贵金属催化剂时，硼氢化反应的范围以及区域和立体选择性都得到了改善。烯炔的不对称硼氢化也可以通过钯催化的反应。近年来，在炔烃的硼氢化反应中，特别是在对映选择性反应中，使用了非贵重的3d金属催化剂，如铁，钴，镍和铜。在这篇综述中，我们研究了炔烃的硼氢化及其机理。
京公网安备 11010802027423号