Rhodium PC_carbeneP complexes 1‐L {L=PPh₃, PPh₂(C₆F₅)} react with isothiocyanate, carbodiimide and disulphide to enable C−S, C−N and S−S bond cleavage. The cleaved molecules are sequestered by the metal center and the pincer alkylidene linkage, forming η²‐coordinated sulfide or imide centered pincer complexes. When a C−S or S−S bond is cleaved, the resulting complexes can bridge two rhodium centers through sulphur forming dimeric complexes and eliminating a monodentate phosphine ligand.

中文翻译：

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铑PCcarbene P钳配合物对CN，CS和SS键的裂解。

铑PC_卡宾P配合物1-L {L = PPh ₃，PPh ₂（C ₆ F ₅）}与异硫氰酸酯，碳化二亚胺和二硫化物反应，可裂解CS，CN和SS键。切割的分子通过金属中心和钳形亚烷基键螯合，形成η ²配位的硫醚或酰亚胺为中心的钳形络合物。当CS键或SS键断裂时，所得的络合物可通过硫桥接两个铑中心，形成二聚体络合物并消除单齿膦配体。