Abstract

The chemistry of metal-organic frameworks (MOF) is intensively developed during the recent years. Such compounds form unique porous structures and demonstrate very interesting functional properties: selective sorption and magnetic, catalytic, luminescence, and many other characteristics. The most part of the studied MOF is homometallic. The heterometallic MOF are studied to a lower extent. Nevertheless, the introduction of a heterometal makes it possible to purposefully modify the properties of the already known structures and also to prepare basically new structures. The results of studies of the synthesis methods of the heterometallic MOF are generalized and reviewed. The main structural types of these compounds and their functional properties are considered.

中文翻译：

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杂金属金属有机骨架合成的主要方法

摘要

近年来，金属有机骨架（MOF）的化学研究得到了大力发展。这样的化合物形成独特的多孔结构，并显示出非常有趣的功能特性：选择性吸附以及磁，催化，发光和许多其他特性。研究的MOF的大部分是同金属的。对杂金属MOF的研究程度较低。然而，通过引入杂金属，可以有目的地改变已知结构的性能，并制备基本上新的结构。综述了异金属MOF合成方法的研究结果。考虑了这些化合物的主要结构类型及其功能特性。