Abstract

Heterogeneous acid-catalyzed organic transformations can be classified as one of the most important aspects of catalysis mostly due to its ability in recycling. This review deals with general discussion on the preparation of sulfonic acid derivatives immobilized on inorganic supports such as silica, periodic mesoporous silica, magnetic nanoparticles, metal organic frameworks, KIT-6, ZSM-5, MCM-41, bentonite, boehmite, clay, and other inorganic supports via organic linker. In addition, application of these inorganic supports in the acceleration of organic transformation is discussed one by one. This review aims to provide an overview of the recent developments in the field of heterogenizing homogeneous catalysts with a particular emphasis on the reaction scope and advantages of heterogeneous solid acid catalysts.

Graphic abstract

中文翻译：

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与无机载体结合的磺酸衍生物的制备和应用的最新进展

摘要

异质酸催化的有机转化可归为催化最重要的方面之一，这主要是由于其具有循环利用的能力。这篇综述涉及固定在无机载体上的磺酸衍生物的一般讨论，所述无机载体如二氧化硅，周期性中孔二氧化硅，磁性纳米粒子，金属有机骨架，KIT-6，ZSM-5，MCM-41，膨润土，勃姆石，粘土，和其他无机载体通过有机连接基。另外，这些无机载体在加速有机转化中的应用被一一讨论。这篇综述旨在概述均相催化剂领域中的最新进展，特别着重于非均相固体酸催化剂的反应范围和优势。

图形摘要