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Visible-Light Photoredox-Catalyzed Amidation of Benzylic Alcohols.
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2020-07-14 , DOI: 10.1021/acs.joc.0c01320
Silvia Gaspa 1 , Andrea Farina 1 , Mariella Tilocca 1 , Andrea Porcheddu 2 , Luisa Pisano 1 , Massimo Carraro 1 , Ugo Azzena 1 , Lidia De Luca 1
Affiliation  

A new photocatalyzed route to amides from alcohols and amines mediated by visible light is presented. The reaction is carried out in ethyl acetate as a solvent. Ethyl acetate can be defined a green and bio-based solvent. The starting materials such as the energy source are easily available, stable, and inexpensive. The reaction has shown to be general and high yielding.

中文翻译:

可见光光氧化还原催化的苄醇酰胺化反应。

提出了一种新的光催化途径,该途径是由可见光介导的由醇和胺转化为酰胺的。该反应在作为溶剂的乙酸乙酯中进行。乙酸乙酯可以定义为绿色和生物基溶剂。诸如能源之类的原材料容易获得,稳定且便宜。该反应显示出一般性和高产率。
更新日期:2020-09-20
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