A simple luminescent sensor BOPM-AB based on arylmaleimide (AM) with 4-methoxyphenyl and N, N-dimethylamino group was designed and synthesized. BOPM-AB exhibits dual spectra response of absorption and emission on Hg²⁺, Cu²⁺ and Fe³⁺. Interestingly, a dynamic response of BOPM-AB was observed upon the stimulus of Cu²⁺ or Fe³⁺. With the prolongation of interaction time, Cu²⁺ and Fe³⁺ make the emission of BOPM-AB become stronger and weaker, respectively. Titration experiments and DFT calculations demonstrate that the dynamic spectra response is closely related to two transfer process: photoinduced electron transfer (PET) from the N, N-dimethylamino to AM, and ligand metal charge transfer (LMCT) induced by metal ions. The unique of properties of BOPM-AB imposes it huge potential in the field of molecular operation. Combined with the factors of different loading amount, sequence of ions and coordinating time, two complex sequential logic systems (half-adder, and keypad lock) could be constructed based on BOPM-AB.

设计并合成了一种基于带有4-甲氧基苯基和N，N-二甲基氨基的芳基马来酰亚胺（AM）的简单发光传感器BOPM-AB 。BOPM-AB在Hg 2 ⁺，Cu ²⁺和Fe ³⁺上表现出吸收和发射的双光谱响应。有趣的是，在刺激Cu ²⁺或Fe ³⁺时，观察到BOPM-AB的动态响应。随着相互作用时间的延长，Cu ²⁺和Fe ^3+分别使BOPM-AB的发射变强。滴定实验和DFT计算表明，动态光谱响应与两个转移过程密切相关：N，N-二甲基氨基与AM的结合以及金属离子诱导的配体金属电荷转移（LMCT）。BOPM-AB的独特性能使其在分子操作领域具有巨大潜力。结合不同的负载量，离子顺序和配位时间等因素，可以基于BOPM-AB构建两个复杂的顺序逻辑系统（半加法器和键盘锁）。